ZACCARIA, FRANCESCO
ZACCARIA, FRANCESCO
DIPARTIMENTO DI SCIENZE CHIMICHE
Catalyst Mileage in Olefin Polymerization: The Peculiar Role of Toluene
2018 Zaccaria, Francesco; Ehm, Christian; Budzelaar, Peter H. M.; Busico, Vincenzo; Cipullo, Roberta; Budzelaar, Petrus Henricus Maria
Internal Donors in Ziegler-Natta Systems: Is Reduction by AlR3 a Requirement for Donor Clean-Up?
2018 Zaccaria, Francesco; Vittoria, Antonio; Correa, Andrea; Ehm, Christian; Budzelaar, Peter H. M.; Busico, Vincenzo; Cipullo, Roberta; Budzelaar, Petrus Henricus Maria
Toluene and α-Olefins as Radical Scavengers: Direct NMR Evidence for Homolytic Chain Transfer Mechanism Leading to Benzyl and "dormant" Titanium Allyl Complexes
2018 Zaccaria, Francesco; Zuccaccia, Cristiano; Cipullo, Roberta; Budzelaar, Peter H. M.; Macchioni, Alceo; Busico, Vincenzo; Ehm, Christian; Budzelaar, Petrus Henricus Maria
Tuning of Barrier Gaps between Competing Reactions – Olefin Polymerization catalysis as an example
2015 Ehm, Christian; Zaccaria, Francesco; Budzelaar, Peter H. M.; Busico, Vincenzo
On The Possibility That Insertion Is Not Always The Rate Limiting Step In Olefin Polymerization
2017 Ehm, Christian; Zaccaria, Francesco; Cipullo, Roberta; Budzelaar, Peter H. M.; Busico, Vincenzo
On The Possibility That Insertion Is Not Always The Rate Limiting Step In Olefin Polymerization
2017 Ehm, Christian; Zaccaria, Francesco; Cipullo, Roberta; Budzelaar, Peter H. M.; Busico, Vincenzo
HTE protocols for the controlled activation of super-active molecular olefin polymerization catalysts in a PPR setup
2019 Mingione, Alessio; Ehm, Christian; Vittoria, Antonio; Zaccaria, Francesco; Cipullo, Roberta; Busico, Vincenzo
Extraction of reliable molecular information from diffusion NMR spectroscopy: hydrodynamic volume or molecular mass?
2019 Zaccaria, Francesco; Zuccaccia, Cristiano; Cipullo, Roberta; Macchioni, Alceo
BHT-modified MAO: cage size estimation, chemical counting of strongly acidic Al-sites and activation of a Ti-phosphinimide precatalyst
2019 Zaccaria, Francesco; Zuccaccia, Cristiano; Cipullo, Roberta; Budzelaar, P. H. M.; Macchioni, Alceo; Busico, Vincenzo; Ehm, Christian
Backbone rearrangement during olefin capture as the rate limiting step in molecular olefin polymerization catalysis and its effect on comonomer affinity
2017 Zaccaria, Francesco; Cipullo, Roberta; Budzelaar, Peter H. M.; Busico, Vincenzo; Ehm, Christian
Chain Transfer to Solvent in Propene Polymerization with Ti Cp-phosphinimide Catalysts: Evidence for Chain Termination via Ti-C Bond Homolysis
2016 Ehm, C; Cipullo, Roberta; Passaro, M; Zaccaria, Francesco; Budzelaar, Petrus Henricus Maria; Busico, Vincenzo
From Mechanistic Investigation to Quantitative Prediction
2019 Ehm, Christian; Zaccaria, Francesco; Cipullo, Roberta
Accurate Prediction of Copolymerization Statistics in Molecular Olefin Polymerization Catalysis: The Role of Entropic, Electronic, and Steric Effects in Catalyst Comonomer Affinity
2017 Zaccaria, Francesco; Ehm, C; Budzelaar, Petrus Henricus Maria; Busico, Vincenzo
Separating Electronic from Steric Effects in Ethene/α-Olefin Copolymerization: A Case Study on Octahedral [ONNO] Zr-Catalysts
2019 Zaccaria, Francesco; Cipullo, Roberta; Correa, Andrea; Budzelaar, P. H. M.; Busico, Vincenzo; Ehm, Christian
High-Throughput Experimentation in Olefin Polymerization Catalysis: Facing the Challenges of Miniaturization
2020 Ehm, C.; Mingione, A.; Vittoria, A.; Zaccaria, F.; Cipullo, R.; Busico, V.
Monitoring the Kinetics of Internal Donor Clean-up from Ziegler-Natta Catalytic Surfaces: An Integrated Experimental and Computational Study
2020 Vittoria, A.; Antinucci, G.; Zaccaria, F.; Cipullo, R.; Busico, V.
Reactivity Trends of Lewis Acidic Sites in Methylaluminoxane and Some of Its Modifications
2020 Zaccaria, F.; Budzelaar, P. H. M.; Cipullo, R.; Zuccaccia, C.; Macchioni, A.; Busico, V.; Ehm, C.
On the Nature of the Lewis Acidic Sites in “TMA-Free” Phenol-Modified Methylaluminoxane
2020 Zaccaria, F.; Zuccaccia, C.; Cipullo, R.; Budzelaar, P. H. M.; Macchioni, A.; Busico, V.; Ehm, C.
Erratum: Monitoring the Kinetics of Internal Donor Clean-up from Ziegler-Natta Catalytic Surfaces: An Integrated Experimental and Computational Study (Journal of Physical Chemistry C (2020) 124: 26 (14245-14252) DOI: 10.1021/acs.jpcc.0c03814)
2020 Vittoria, A.; Antinucci, G.; Zaccaria, F.; Cipullo, R.; Busico, V.
Methylaluminoxane’s Molecular Cousin: A Well-defined and “Complete” Al-Activator for Molecular Olefin Polymerization Catalysts
2021 Zaccaria, Francesco; Zuccaccia, Cristiano; Cipullo, Roberta; Budzelaar, Peter H. M.; Vittoria, Antonio; Macchioni, Alceo; Busico, Vincenzo; Ehm, Christian
Titolo | Tipologia | Data di pubblicazione | Autore(i) | File |
---|---|---|---|---|
Catalyst Mileage in Olefin Polymerization: The Peculiar Role of Toluene | 1.1 Articolo in rivista | 2018 | Zaccaria, Francesco; Ehm, Christian; Budzelaar, Peter H. M.; Busico, Vincenzo; Cipullo, Roberta; Budzelaar, Petrus Henricus Maria | |
Internal Donors in Ziegler-Natta Systems: Is Reduction by AlR3 a Requirement for Donor Clean-Up? | 1.1 Articolo in rivista | 2018 | Zaccaria, Francesco; Vittoria, Antonio; Correa, Andrea; Ehm, Christian; Budzelaar, Peter H. M.; Busico, Vincenzo; Cipullo, Roberta; Budzelaar, Petrus Henricus Maria | |
Toluene and α-Olefins as Radical Scavengers: Direct NMR Evidence for Homolytic Chain Transfer Mechanism Leading to Benzyl and "dormant" Titanium Allyl Complexes | 1.1 Articolo in rivista | 2018 | Zaccaria, Francesco; Zuccaccia, Cristiano; Cipullo, Roberta; Budzelaar, Peter H. M.; Macchioni, Alceo; Busico, Vincenzo; Ehm, Christian; Budzelaar, Petrus Henricus Maria | |
Tuning of Barrier Gaps between Competing Reactions – Olefin Polymerization catalysis as an example | 4.3 Poster | 2015 | Ehm, Christian; Zaccaria, Francesco; Budzelaar, Peter H. M.; Busico, Vincenzo | |
On The Possibility That Insertion Is Not Always The Rate Limiting Step In Olefin Polymerization | 4.3 Poster | 2017 | Ehm, Christian; Zaccaria, Francesco; Cipullo, Roberta; Budzelaar, Peter H. M.; Busico, Vincenzo | |
On The Possibility That Insertion Is Not Always The Rate Limiting Step In Olefin Polymerization | 4.2 Abstract in Atti di convegno | 2017 | Ehm, Christian; Zaccaria, Francesco; Cipullo, Roberta; Budzelaar, Peter H. M.; Busico, Vincenzo | |
HTE protocols for the controlled activation of super-active molecular olefin polymerization catalysts in a PPR setup | 4.3 Poster | 2019 | Mingione, Alessio; Ehm, Christian; Vittoria, Antonio; Zaccaria, Francesco; Cipullo, Roberta; Busico, Vincenzo | |
Extraction of reliable molecular information from diffusion NMR spectroscopy: hydrodynamic volume or molecular mass? | 1.1 Articolo in rivista | 2019 | Zaccaria, Francesco; Zuccaccia, Cristiano; Cipullo, Roberta; Macchioni, Alceo | |
BHT-modified MAO: cage size estimation, chemical counting of strongly acidic Al-sites and activation of a Ti-phosphinimide precatalyst | 1.1 Articolo in rivista | 2019 | Zaccaria, Francesco; Zuccaccia, Cristiano; Cipullo, Roberta; Budzelaar, P. H. M.; Macchioni, Alceo; Busico, Vincenzo; Ehm, Christian | |
Backbone rearrangement during olefin capture as the rate limiting step in molecular olefin polymerization catalysis and its effect on comonomer affinity | 1.1 Articolo in rivista | 2017 | Zaccaria, Francesco; Cipullo, Roberta; Budzelaar, Peter H. M.; Busico, Vincenzo; Ehm, Christian | |
Chain Transfer to Solvent in Propene Polymerization with Ti Cp-phosphinimide Catalysts: Evidence for Chain Termination via Ti-C Bond Homolysis | 1.1 Articolo in rivista | 2016 | Ehm, C; Cipullo, Roberta; Passaro, M; Zaccaria, Francesco; Budzelaar, Petrus Henricus Maria; Busico, Vincenzo | |
From Mechanistic Investigation to Quantitative Prediction | 2.1 Contributo in volume (Capitolo o Saggio) | 2019 | Ehm, Christian; Zaccaria, Francesco; Cipullo, Roberta | |
Accurate Prediction of Copolymerization Statistics in Molecular Olefin Polymerization Catalysis: The Role of Entropic, Electronic, and Steric Effects in Catalyst Comonomer Affinity | 1.1 Articolo in rivista | 2017 | Zaccaria, Francesco; Ehm, C; Budzelaar, Petrus Henricus Maria; Busico, Vincenzo | |
Separating Electronic from Steric Effects in Ethene/α-Olefin Copolymerization: A Case Study on Octahedral [ONNO] Zr-Catalysts | 1.1 Articolo in rivista | 2019 | Zaccaria, Francesco; Cipullo, Roberta; Correa, Andrea; Budzelaar, P. H. M.; Busico, Vincenzo; Ehm, Christian | |
High-Throughput Experimentation in Olefin Polymerization Catalysis: Facing the Challenges of Miniaturization | 1.1 Articolo in rivista | 2020 | Ehm, C.; Mingione, A.; Vittoria, A.; Zaccaria, F.; Cipullo, R.; Busico, V. | |
Monitoring the Kinetics of Internal Donor Clean-up from Ziegler-Natta Catalytic Surfaces: An Integrated Experimental and Computational Study | 1.1 Articolo in rivista | 2020 | Vittoria, A.; Antinucci, G.; Zaccaria, F.; Cipullo, R.; Busico, V. | |
Reactivity Trends of Lewis Acidic Sites in Methylaluminoxane and Some of Its Modifications | 1.1 Articolo in rivista | 2020 | Zaccaria, F.; Budzelaar, P. H. M.; Cipullo, R.; Zuccaccia, C.; Macchioni, A.; Busico, V.; Ehm, C. | |
On the Nature of the Lewis Acidic Sites in “TMA-Free” Phenol-Modified Methylaluminoxane | 1.1 Articolo in rivista | 2020 | Zaccaria, F.; Zuccaccia, C.; Cipullo, R.; Budzelaar, P. H. M.; Macchioni, A.; Busico, V.; Ehm, C. | |
Erratum: Monitoring the Kinetics of Internal Donor Clean-up from Ziegler-Natta Catalytic Surfaces: An Integrated Experimental and Computational Study (Journal of Physical Chemistry C (2020) 124: 26 (14245-14252) DOI: 10.1021/acs.jpcc.0c03814) | 1.7 Commento, erratum, replica e simili | 2020 | Vittoria, A.; Antinucci, G.; Zaccaria, F.; Cipullo, R.; Busico, V. | |
Methylaluminoxane’s Molecular Cousin: A Well-defined and “Complete” Al-Activator for Molecular Olefin Polymerization Catalysts | 1.1 Articolo in rivista | 2021 | Zaccaria, Francesco; Zuccaccia, Cristiano; Cipullo, Roberta; Budzelaar, Peter H. M.; Vittoria, Antonio; Macchioni, Alceo; Busico, Vincenzo; Ehm, Christian |