HTE methods and results in PO catalysis and materials characterization

High Throughput Experimentation (HTE) was originally introduced in olefin polymerization R&D as a discovery tool. In recent years, we spent a considerable effort to extend the scope of the HTE approach to mechanistic investigations. A high-performance polymerization platform (Freeslate PPR48) was integrated with state-of-art polymer characterization tools (including GPC, 13C NMR and A-CEF), and the resulting workflow was optimized for the fast acquisition of large structure-properties databases usable in QSAR studies. The workflow was successfully applied to Ziegler-Natta and molecular olefin polymerization systems and products thereof.(1) In this presentation, we will illustrate case histories of increasing complexity, covering molecular kinetics as well as polymer characterization aspects.