Oxidative addition reactions of Pd(PPh3)4 on the pyrimidine nucleosides 3',5'-di-Oacetylthymidine and 3',5'-di-O-acetyl-4-chlorothymidine and on the nucleobase 1-methylthymine have been investigated. N3 and C4 metal coordinated complexes 3 and 7 were isolated and characterized by spectroscopic techniques. Moreover, the crystal structure of the trans- [PdCl(1-methyl thymine)(PPh3)2]H2O is reported.
REACTIONS OF Pd(PPH3)4 WITH 3',5'-DI-O-ACETYLTHYMIDINE: OXIDATIVE ADDITION OF Pd(PPH3)4 ON THYMIDINE N3 AND C4 ATOMS / Romanelli, Alessandra; R., Iacovino; Piccialli, Gennaro; Ruffo, Francesco; DE NAPOLI, Lorenzo; Pedone, Carlo; B., DI BLASIO; A., Messere. - In: ORGANOMETALLICS. - ISSN 0276-7333. - STAMPA. - 24:14(2005), pp. 3401-3408. [10.1021/om050058s]
REACTIONS OF Pd(PPH3)4 WITH 3',5'-DI-O-ACETYLTHYMIDINE: OXIDATIVE ADDITION OF Pd(PPH3)4 ON THYMIDINE N3 AND C4 ATOMS
ROMANELLI, ALESSANDRA;PICCIALLI, GENNARO;RUFFO, FRANCESCO;DE NAPOLI, LORENZO;PEDONE, CARLO;
2005
Abstract
Oxidative addition reactions of Pd(PPh3)4 on the pyrimidine nucleosides 3',5'-di-Oacetylthymidine and 3',5'-di-O-acetyl-4-chlorothymidine and on the nucleobase 1-methylthymine have been investigated. N3 and C4 metal coordinated complexes 3 and 7 were isolated and characterized by spectroscopic techniques. Moreover, the crystal structure of the trans- [PdCl(1-methyl thymine)(PPh3)2]H2O is reported.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
