Reported herein is the assignment of the absolute stereochemistry of oxazinin-1, a cytotoxic compound recently isolated from the digestive glands of Mytilus galloprovincialis of the North Adriatic Sea. The recent 9-AMA shift-correlation method for assigning absolute configuration to -chiral primary alcohols was employed and preparatory Molecular Mechanics calculations were carried out.
Assignment of the absolute stereochemistry of oxazinin-1: application of the 9-AMA shift-correlation method for b-chiral primary alcohols / Ciminiello, Patrizia; Dell'Aversano, Carmela; Fattorusso, Caterina; Fattorusso, Ernesto; Forino, Martino; S., Magno. - In: TETRAHEDRON. - ISSN 0040-4020. - STAMPA. - 57:(2001), pp. 8189-8192. [10.1016/S0040-4020(01)00795-5]
Assignment of the absolute stereochemistry of oxazinin-1: application of the 9-AMA shift-correlation method for b-chiral primary alcohols
CIMINIELLO, PATRIZIA;DELL'AVERSANO, CARMELA;FATTORUSSO, CATERINA;FATTORUSSO, ERNESTO
;FORINO, MARTINO;
2001
Abstract
Reported herein is the assignment of the absolute stereochemistry of oxazinin-1, a cytotoxic compound recently isolated from the digestive glands of Mytilus galloprovincialis of the North Adriatic Sea. The recent 9-AMA shift-correlation method for assigning absolute configuration to -chiral primary alcohols was employed and preparatory Molecular Mechanics calculations were carried out.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
