The reactivity of cationic Pt-II-phenyl complexes of the type [PtPh(CH2=CHR)(phen)](+) (R = H or Me) has been investigated. In all cases, insertion of the alkene into the Pt-Ph bond has been observed. The fate of the resulting Pt-CH2CHRPh (R = H or Me) derivative depends on the experimental conditions. In the presence of donor ligands (e.g. excess olefin, pyridine or triphenylphosphine) the product is stable, while in the absence of them a rapid rearrangement to form Pt-C6H4(CHRMe)-2 occurs.
The regiochemical control of a Pt-promoted alkylation of the phenyl ring / Cucciolito, MARIA ELENA; DE RENZI, A; Orabona, I; Ruffo, Francesco; Tesauro, Diego. - In: JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS. - ISSN 0300-9246. - STAMPA. - 10(1998), pp. 1675-1678. [10.1039/a800603b]
The regiochemical control of a Pt-promoted alkylation of the phenyl ring
CUCCIOLITO, MARIA ELENA;RUFFO, FRANCESCO;TESAURO, DIEGO
1998
Abstract
The reactivity of cationic Pt-II-phenyl complexes of the type [PtPh(CH2=CHR)(phen)](+) (R = H or Me) has been investigated. In all cases, insertion of the alkene into the Pt-Ph bond has been observed. The fate of the resulting Pt-CH2CHRPh (R = H or Me) derivative depends on the experimental conditions. In the presence of donor ligands (e.g. excess olefin, pyridine or triphenylphosphine) the product is stable, while in the absence of them a rapid rearrangement to form Pt-C6H4(CHRMe)-2 occurs.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
