The title compound, C12H24O3, was prepared by the RuO4- catalyzed oxidative cyclization of 2,9-dimethyldeca-2,8-diene. The crystal structure determination has shown unambigously that ring closure produced the trans stereoisomer. Intramolecular O—H O hydrogen bonding generates an S(8) ring motif. Intermolecular O—H O hydrogen bonding leads to the formation of infinite C2 2(4) chains running along the a axis.
rac-2,7-Bis(2-hydroxy-2-propyl)-trans-oxepane / Centore, Roberto; Piccialli, Vincenzo; Tuzi, Angela. - In: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE. - ISSN 1600-5368. - ELETTRONICO. - E63:(2007), pp. 02907-02908. [10.1107/S1600536807022428]
rac-2,7-Bis(2-hydroxy-2-propyl)-trans-oxepane
CENTORE, ROBERTO;PICCIALLI, VINCENZO;TUZI, ANGELA
2007
Abstract
The title compound, C12H24O3, was prepared by the RuO4- catalyzed oxidative cyclization of 2,9-dimethyldeca-2,8-diene. The crystal structure determination has shown unambigously that ring closure produced the trans stereoisomer. Intramolecular O—H O hydrogen bonding generates an S(8) ring motif. Intermolecular O—H O hydrogen bonding leads to the formation of infinite C2 2(4) chains running along the a axis.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
