A unified convenient strategy for the synthesis of 5,6-dihydroxyindole-derived 2,7'-, 2,2'-, and 2,3'-biindolyls (e.g. I) is reported, which is based on proper manipulation of key o-ethynylaniline precursors. By the same methodol. 5,6-diacetoxy-7-iodoindole can also be obtained in good yield.
Efficient Synthesis of 5,6-Dihydroxyindole Dimers, Key Eumelanin Building Blocks, by a Unified o-Ethynylaniline-Based Strategy for the Construction of 2-Linked Biindolyl Scaffolds / Capelli, L.; Manini, Paola; Pezzella, Alessandro; Napolitano, Alessandra; D'Ischia, Marco. - In: JOURNAL OF ORGANIC CHEMISTRY. - ISSN 0022-3263. - STAMPA. - 74:18(2009), pp. 7191-7194. [10.1021/jo901259s]
Efficient Synthesis of 5,6-Dihydroxyindole Dimers, Key Eumelanin Building Blocks, by a Unified o-Ethynylaniline-Based Strategy for the Construction of 2-Linked Biindolyl Scaffolds.
MANINI, PAOLA;PEZZELLA, ALESSANDRO;NAPOLITANO, ALESSANDRA;D'ISCHIA, MARCO
2009
Abstract
A unified convenient strategy for the synthesis of 5,6-dihydroxyindole-derived 2,7'-, 2,2'-, and 2,3'-biindolyls (e.g. I) is reported, which is based on proper manipulation of key o-ethynylaniline precursors. By the same methodol. 5,6-diacetoxy-7-iodoindole can also be obtained in good yield.| File | Dimensione | Formato | |
|---|---|---|---|
|
text joc note.pdf
non disponibili
Tipologia:
Documento in Post-print
Licenza:
Accesso privato/ristretto
Dimensione
817.22 kB
Formato
Adobe PDF
|
817.22 kB | Adobe PDF | Visualizza/Apri Richiedi una copia |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
