Photooxygenation of differently functionalized furans is investigated in aqueous solutions and in ionic liquids [emim]Br and [bmim]BF4. The reaction is generally selective and the final products derive from rearrangement of the intermediate endoperoxides, depending mainly on the polarity and/or nucleophilic nature of the solvent.
Photooxygenation of furans in water and ionic liquid solutions / A., Astarita; Cermola, Flavio; DELLA GRECA, Marina; Iesce, MARIA ROSARIA; Previtera, Lucio; M., Rubino. - In: GREEN CHEMISTRY. - ISSN 1463-9262. - STAMPA. - 11(2009), pp. 2030-2033.
Photooxygenation of furans in water and ionic liquid solutions
CERMOLA, FLAVIO;DELLA GRECA, MARINA;IESCE, MARIA ROSARIA;PREVITERA, LUCIO;
2009
Abstract
Photooxygenation of differently functionalized furans is investigated in aqueous solutions and in ionic liquids [emim]Br and [bmim]BF4. The reaction is generally selective and the final products derive from rearrangement of the intermediate endoperoxides, depending mainly on the polarity and/or nucleophilic nature of the solvent.File in questo prodotto:
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