Scanning Tunneling Spectroscopy study of paramagnetic superconducting β’’-ET4[(H3O)Fe(C2O4)3]•C6H5Br crystals

Scanning tunnelling spectroscopy (STS) and microscopy (STM) were performed on the paramagnetic molecular superconductor beta''-ET4[(H3O)Fe(C2O4)(3)]C6H5Br. Under ambient pressure, this compound is located near the boundary separating superconducting and insulating phases of the phase diagram. In spite of a strongly reduced critical temperature T-c (T-c = 4.0 K at the onset, zero resistance at T-c = 0.5 K), the low temperature STS spectra taken in the superconducting regions show strong similarities with the higher T-c ET kappa-derivatives series. We exploited different models for the density of states (DOS), with conventional and unconventional order parameters to take into account the role played by possible magnetic and non-magnetic disorder in the superconducting order parameter. The values of the superconducting order parameter obtained by the fitting procedure are close to the ones obtained on more metallic and higher T-c organic crystals and far above the BCS values, suggesting an intrinsic role of disorder in the superconductivity of organic superconductors and a further confirmation of the non-conventional superconductivity in such compounds.