A new synthetic catalyst, capable of acting like an enzyme in the accomplishment of direct aldol reactions, is presented. Excellent results, in terms of chemical yields and diastereo-/enantiomeric ratios, are reported for the catalyzed additions of cyclohexanone to variously substituted benzaldehydes.
Diastereo- and Enantioselective Direct Aldol Reactions inAqueous Medium: a New Highly Efficient Proline-SugarChimeric Catalyst / Pedatella, Silvana; DE NISCO, Mauro; D., Mastroianni; Naviglio, Daniele; A., Nucci; Caputo, Romualdo. - In: ADVANCED SYNTHESIS & CATALYSIS. - ISSN 1615-4150. - 353:9(2011), pp. 1443-1446. [10.1002/adsc.201100143]
Diastereo- and Enantioselective Direct Aldol Reactions inAqueous Medium: a New Highly Efficient Proline-SugarChimeric Catalyst
PEDATELLA, SILVANA;DE NISCO, MAURO;NAVIGLIO, DANIELE;CAPUTO, ROMUALDO
2011
Abstract
A new synthetic catalyst, capable of acting like an enzyme in the accomplishment of direct aldol reactions, is presented. Excellent results, in terms of chemical yields and diastereo-/enantiomeric ratios, are reported for the catalyzed additions of cyclohexanone to variously substituted benzaldehydes.| File | Dimensione | Formato | |
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