UV-visible absorption spectroelectrochemistry elucidated the different redox behaviours of FeIII- and CoIII-mimochrome VI artificial enzymes, adsorbed on mesoporous conductive films of ITO. The reduction of the ferric complex was rapid and reversible, while the cobaltic complex exhibited irreversible processes probably related to multiple coordination states.
Spectroelectrochemistry of Fe(III)- and Co(III)- mimochrome VI artificial enzymes immobilized on mesoporous ITO electrodes / Vitale, Rosa; Lista, Liliana; S., Lau Truong; R. T., Tucker; M. J., Brett; B., Limoges; Pavone, Vincenzo; Lombardi, Angelina; V., Balland. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 50:(2014), pp. 1894-1896. [10.1039/c3cc48489k]
Spectroelectrochemistry of Fe(III)- and Co(III)- mimochrome VI artificial enzymes immobilized on mesoporous ITO electrodes
VITALE, ROSA;LISTA, LILIANA;PAVONE, VINCENZO;LOMBARDI, ANGELINA
;
2014
Abstract
UV-visible absorption spectroelectrochemistry elucidated the different redox behaviours of FeIII- and CoIII-mimochrome VI artificial enzymes, adsorbed on mesoporous conductive films of ITO. The reduction of the ferric complex was rapid and reversible, while the cobaltic complex exhibited irreversible processes probably related to multiple coordination states.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
