A perimidine with four donor sites, 2-(2-methyl-2,3-dihydro-1H-perimidin-2- yl)benzene-1,3-diol has been prepared through InCl3 catalysis from commercial precursors. It exhibits in solid state a bent structure, with two ring systems substantially orthogonal. A ruthenium(II) complex catalyzes the transfer hydrogenation of phenylalkyl ketones by isopropanol with good efficiency
Preparation, structure, and metal coordination of 2-(2-methyl-2,3-dihydro- 1H-perimidin-2-yl)benzene-1,3-diol / Cucciolito, MARIA ELENA; Panunzi, Barbara; Ruffo, Francesco; Tuzi, Angela. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 54:(2013), pp. 1053-1056. [10.1016/j.tetlet.2012.12.088]
Preparation, structure, and metal coordination of 2-(2-methyl-2,3-dihydro- 1H-perimidin-2-yl)benzene-1,3-diol
CUCCIOLITO, MARIA ELENA;PANUNZI, BARBARA;RUFFO, FRANCESCO;TUZI, ANGELA
2013
Abstract
A perimidine with four donor sites, 2-(2-methyl-2,3-dihydro-1H-perimidin-2- yl)benzene-1,3-diol has been prepared through InCl3 catalysis from commercial precursors. It exhibits in solid state a bent structure, with two ring systems substantially orthogonal. A ruthenium(II) complex catalyzes the transfer hydrogenation of phenylalkyl ketones by isopropanol with good efficiencyI documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
