An iminic derivative of 2-amino-6-methylbenzothiazole, able to generate on deprotonation a mononegative ligand moiety and the corresponding tetracoordinate zinc (II) complex are reported. The complex is centrosymmetrical and difunctionalized with two OH groups that have been used for omo- and co-polymerisation with a diisocyanate to form four polyurethanes with various zinc content.
Fluorescent metallopolymers with Zn(II) in a Schiff base/phenoxide coordination environment / Caruso, Ugo; Panunzi, Barbara; Roviello, Antonio; Tuzi, Angela. - In: INORGANIC CHEMISTRY COMMUNICATIONS. - ISSN 1387-7003. - 29:(2013), pp. 138-140. [10.1016/j.inoche.2012.11.037]
Fluorescent metallopolymers with Zn(II) in a Schiff base/phenoxide coordination environment
CARUSO, UGO;PANUNZI, BARBARA;ROVIELLO, ANTONIO;TUZI, ANGELA
2013
Abstract
An iminic derivative of 2-amino-6-methylbenzothiazole, able to generate on deprotonation a mononegative ligand moiety and the corresponding tetracoordinate zinc (II) complex are reported. The complex is centrosymmetrical and difunctionalized with two OH groups that have been used for omo- and co-polymerisation with a diisocyanate to form four polyurethanes with various zinc content.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
