Two classes of hydrophilic Pd0 complexes containing P,N and N,N sugar‐based ligands were prepared and tested in the Suzuki–Miyaura cross‐coupling reaction under environmentally friendly aqueous conditions. The best catalyst was tolerant towards different substrates, and its activity is comparable with the highest values reported so far for reactions in aqueous media [loading 0.0010 %, turnover frequency (TOF) 3.5 × 104 h–1].
Hydrophilic Pd0Complexes Based on Sugars for Efficient Suzuki-Miyaura Coupling in Aqueous Systems / Giulia, Tarantino; Massimiliano, Curcio; Andrea, Pica; Carpentieri, Andrea; Cucciolito, MARIA ELENA; Ruffo, Francesco; Vitagliano, Aldo; Matteo, Lega. - In: EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. - ISSN 1434-1948. - 2014:(2014), pp. 4199-4208. [10.1002/ejic.201402456]
Hydrophilic Pd0Complexes Based on Sugars for Efficient Suzuki-Miyaura Coupling in Aqueous Systems
CARPENTIERI, ANDREA;CUCCIOLITO, MARIA ELENA;RUFFO, FRANCESCO;VITAGLIANO, ALDO;
2014
Abstract
Two classes of hydrophilic Pd0 complexes containing P,N and N,N sugar‐based ligands were prepared and tested in the Suzuki–Miyaura cross‐coupling reaction under environmentally friendly aqueous conditions. The best catalyst was tolerant towards different substrates, and its activity is comparable with the highest values reported so far for reactions in aqueous media [loading 0.0010 %, turnover frequency (TOF) 3.5 × 104 h–1].| File | Dimensione | Formato | |
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