We introduce a (non-standard) laplacian form producing squared angular momentum values equal to ћ2[ l(l+1)+1/4]. So we set up an ”alternative” Hydrogen atom model, which can also be thought as a sort of precursor to the standard quantum atom. It shows the following properties : torus-like orbitals ; appearance of a ”zero point” rotational quantum number (it adds zenithal altitude fluctuations with momentum ћ/2); S-like wavefunctions made zero over nucleus; corrections to spectroscopic terms, linearly dependent on the operators ˆlz and ˆl^2ns, identical to the standard ones ; quantization procedure resolvable into a quantization in the constant azimuth plane, followed by rotation around the polar axis. Although we come to a subtlety concerning the azimuthal component, these features make the model suitable for decomposition in one-dimensional motions, whose quantum properties we could recently approach by a method based on ergodic statistics of classical-like time laws with variable mass. Comparing the present results with the standard quantum theory and the corresponding quasi-classical case, we trace a possible path to implement our one-dimensional calculations up to describe 2D and 3D motions; and to identify some ultimate differences, worth of further investigation, with those standard models.

An alternative quantization procedure for the Hydrogen atom / Mastrocinque, Giuseppe. - In: ANNALES DE LA FONDATION LOUIS DE BROGLIE. - ISSN 0182-4295. - 38:(2013), pp. 83-112.

An alternative quantization procedure for the Hydrogen atom

MASTROCINQUE, GIUSEPPE
2013

Abstract

We introduce a (non-standard) laplacian form producing squared angular momentum values equal to ћ2[ l(l+1)+1/4]. So we set up an ”alternative” Hydrogen atom model, which can also be thought as a sort of precursor to the standard quantum atom. It shows the following properties : torus-like orbitals ; appearance of a ”zero point” rotational quantum number (it adds zenithal altitude fluctuations with momentum ћ/2); S-like wavefunctions made zero over nucleus; corrections to spectroscopic terms, linearly dependent on the operators ˆlz and ˆl^2ns, identical to the standard ones ; quantization procedure resolvable into a quantization in the constant azimuth plane, followed by rotation around the polar axis. Although we come to a subtlety concerning the azimuthal component, these features make the model suitable for decomposition in one-dimensional motions, whose quantum properties we could recently approach by a method based on ergodic statistics of classical-like time laws with variable mass. Comparing the present results with the standard quantum theory and the corresponding quasi-classical case, we trace a possible path to implement our one-dimensional calculations up to describe 2D and 3D motions; and to identify some ultimate differences, worth of further investigation, with those standard models.
2013
An alternative quantization procedure for the Hydrogen atom / Mastrocinque, Giuseppe. - In: ANNALES DE LA FONDATION LOUIS DE BROGLIE. - ISSN 0182-4295. - 38:(2013), pp. 83-112.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11588/587442
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