The reaction of N-methyl-N-tert-butyldimethylsilyltrifluoroacetamide with arginine proceeds with cleavage of the guanidino group, producing a mixture of the tert-butyldimethylsilyl derivatives of ornithine and carbodiimide. These compounds are identified by analysing the reaction mixture using gas chromatography/mass spectrometry.
Transformation of arginine into ornithine during the preparation of its tert‐butyldimethylsilyl derivative for analysis by gas chromatography/mass spectrometry / G., Corso; M., Esposito; Gallo, Monica; Ad, Russo; M., Antonio. - In: BIOLOGICAL MASS SPECTROMETRY. - ISSN 1052-9306. - 22:12(1993), pp. 698-702.
Transformation of arginine into ornithine during the preparation of its tert‐butyldimethylsilyl derivative for analysis by gas chromatography/mass spectrometry
GALLO, MONICA;
1993
Abstract
The reaction of N-methyl-N-tert-butyldimethylsilyltrifluoroacetamide with arginine proceeds with cleavage of the guanidino group, producing a mixture of the tert-butyldimethylsilyl derivatives of ornithine and carbodiimide. These compounds are identified by analysing the reaction mixture using gas chromatography/mass spectrometry.File in questo prodotto:
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