In this work we investigate the sorption of CO2 in a formulated polyether polyol, typically used to obtain rigid polyurethane foams when it reacts with isocyanates. In particular, by using a fully-experimental, coupled gravimetry-Axisymmetric Drop Shape Analysis, solubility, mutual diffusivity, specific volume and interfacial tension of polyol/CO2 solutions have been measured at 35 C and at CO2 pressures up to 8000 kPa. CO2-treated polyol was also subjected to Gel Permeation Chromatography (GPC) and Fourier Trans- form Infrared (FT-IR) spectroscopic analysis to evaluate the effect of the high-CO2 pressure treatment. The results show quite a large CO2 solubilization (up to 17% ca. in the examined experimental range), in turn responsible for a moderate swelling of the polymer and an extensive effect on the interfacial ten- sion, which reaches vanishing values at the highest investigated pressure.

Polyether polyol/CO2 solutions: Solubility, mutual diffusivity, specific volume and interfacial tension by coupled gravimetry-Axisymmetric Drop Shape Analysis / DI CAPRIO, MARIA ROSARIA; DAL POGGETTO, Giovanni; PASTORE CARBONE, MARIA GIOVANNA; DI MAIO, Ernesto; Cavalca, Sara; Parenti, Vanni; Iannace, Salvatore. - In: FLUID PHASE EQUILIBRIA. - ISSN 0378-3812. - 425:(2016), pp. 342-350. [10.1016/j.fluid.2016.06.023]

Polyether polyol/CO2 solutions: Solubility, mutual diffusivity, specific volume and interfacial tension by coupled gravimetry-Axisymmetric Drop Shape Analysis

DI CAPRIO, MARIA ROSARIA;DAL POGGETTO, GIOVANNI;PASTORE CARBONE, MARIA GIOVANNA;DI MAIO, ERNESTO;IANNACE, Salvatore
2016

Abstract

In this work we investigate the sorption of CO2 in a formulated polyether polyol, typically used to obtain rigid polyurethane foams when it reacts with isocyanates. In particular, by using a fully-experimental, coupled gravimetry-Axisymmetric Drop Shape Analysis, solubility, mutual diffusivity, specific volume and interfacial tension of polyol/CO2 solutions have been measured at 35 C and at CO2 pressures up to 8000 kPa. CO2-treated polyol was also subjected to Gel Permeation Chromatography (GPC) and Fourier Trans- form Infrared (FT-IR) spectroscopic analysis to evaluate the effect of the high-CO2 pressure treatment. The results show quite a large CO2 solubilization (up to 17% ca. in the examined experimental range), in turn responsible for a moderate swelling of the polymer and an extensive effect on the interfacial ten- sion, which reaches vanishing values at the highest investigated pressure.
2016
Polyether polyol/CO2 solutions: Solubility, mutual diffusivity, specific volume and interfacial tension by coupled gravimetry-Axisymmetric Drop Shape Analysis / DI CAPRIO, MARIA ROSARIA; DAL POGGETTO, Giovanni; PASTORE CARBONE, MARIA GIOVANNA; DI MAIO, Ernesto; Cavalca, Sara; Parenti, Vanni; Iannace, Salvatore. - In: FLUID PHASE EQUILIBRIA. - ISSN 0378-3812. - 425:(2016), pp. 342-350. [10.1016/j.fluid.2016.06.023]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11588/642676
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