Graphene wetting by polymers is a critical issue to both the success of polymer-aided transfer of large size sheets onto specific substrates and to the development of well performing nanocomposites. Here we show for the first time that high temperature contact angle measurements can be performed to investigate the wettability of CVD graphene by molten polymers. In particular, poly(methyl methacrylate), a widely used polymer support for CVD graphene transfer, has been adopted herein for this proof-of-concept study and the values of contact angle and work of adhesion have been provided in the temperature range 170–200 °C.
Wettability of graphene by molten polymers / PASTORE CARBONE, MARIA GIOVANNA; Tammaro, Daniele; C Manikas, Anastasios; Paterakis, George; DI MAIO, Ernesto; Galiotis, Costas. - In: POLYMER. - ISSN 0032-3861. - 180:(2019), pp. 121708-121713. [10.1016/j.polymer.2019.121708]
Wettability of graphene by molten polymers
Maria Giovanna Pastore Carbone;Daniele Tammaro;Ernesto Di Maio
;
2019
Abstract
Graphene wetting by polymers is a critical issue to both the success of polymer-aided transfer of large size sheets onto specific substrates and to the development of well performing nanocomposites. Here we show for the first time that high temperature contact angle measurements can be performed to investigate the wettability of CVD graphene by molten polymers. In particular, poly(methyl methacrylate), a widely used polymer support for CVD graphene transfer, has been adopted herein for this proof-of-concept study and the values of contact angle and work of adhesion have been provided in the temperature range 170–200 °C.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.