An unprecedented direct oxidation of high-oleic triglycerides to produce azelaic glycerides has been carried out by using a catalytic system based on H2WO4/H2O2. The results are highly competitive with those reported so far for simpler feedstock: at low catalyst loading the oxidation proceeds with satisfactory yields also starting from a real waste oil matrix without any prior purification.
Direct and Solvent-Free Oxidative Cleavage of Double Bonds in High-Oleic Vegetable Oils / Melchiorre, M.; Benessere, V.; Cucciolito, M. E.; Melchiorre, C.; Ruffo, F.; Esposito, R.. - In: CHEMISTRYSELECT. - ISSN 2365-6549. - 5:4(2020), pp. 1396-1400. [10.1002/slct.201903516]
Direct and Solvent-Free Oxidative Cleavage of Double Bonds in High-Oleic Vegetable Oils
Melchiorre M.;Cucciolito M. E.;Melchiorre C.;Ruffo F.
;Esposito R.
2020
Abstract
An unprecedented direct oxidation of high-oleic triglycerides to produce azelaic glycerides has been carried out by using a catalytic system based on H2WO4/H2O2. The results are highly competitive with those reported so far for simpler feedstock: at low catalyst loading the oxidation proceeds with satisfactory yields also starting from a real waste oil matrix without any prior purification.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
