Oxidation by ground‐state molecular oxygen of fully substituted alkoxyoxazoles I gave imines IV as major products; diacylcarbamates III were also obtained as minor products. The free radical nature of the autoxidation was established. A mechanistic interpretation of the results is suggested also in the light of the results of the oxidation with singlet oxygen. Copyright © 1977 Journal of Heterocyclic Chemistry
Comparison between triplet and singlet molecular oxygen oxidation of fully substituted alkoxyoxazoles / Graziano, M. L.; Carotenuto, A. T.; Iesce, M. R.; Scarpati, R.. - In: JOURNAL OF HETEROCYCLIC CHEMISTRY. - ISSN 0022-152X. - 14:7(1977), pp. 1215-1219. [10.1002/jhet.5570140717]
Comparison between triplet and singlet molecular oxygen oxidation of fully substituted alkoxyoxazoles
Graziano M. L.;Iesce M. R.;
1977
Abstract
Oxidation by ground‐state molecular oxygen of fully substituted alkoxyoxazoles I gave imines IV as major products; diacylcarbamates III were also obtained as minor products. The free radical nature of the autoxidation was established. A mechanistic interpretation of the results is suggested also in the light of the results of the oxidation with singlet oxygen. Copyright © 1977 Journal of Heterocyclic ChemistryI documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
