Aqueous solutions of indocyanine green (ICG) are spectrophotometrically and fluorimetrically studied as a function of the dye concentration. The integral absorbance concept is introduced to minimize uncertainties due to the use of only a point. This new method, provides a value of the equilibrium constant consistent with those obtained, by a different method, for safranine and thionine. The influence of ICG concentration on its fluorescence spectrum is determined. When ICG is exposed to white light degrades through the formation of free radicals. The overall kinetics of degradation is monitored spectrophotometrically and studied in an unconventional way. The results exhibit a power law, regardless of the initial concentration of dye. An apparent order of 1.5 suggests a complex mechanism where the collision between radicals is very important whilst a lifetime of 4 h it is indicative of a rapid degradation kinetics.

Thermodynamic properties and photodegradation kinetics of indocyanine green in aqueous solution / DI NEZZA, Francesca; Guerra, Germano; Costagliola, Ciro; Zeppa, L.; Ambrosone, Luigi. - In: DYES AND PIGMENTS. - ISSN 0143-7208. - 134:(2016), pp. 342-347. [10.1016/j.dyepig.2016.06.012]

Thermodynamic properties and photodegradation kinetics of indocyanine green in aqueous solution

GUERRA, Germano;COSTAGLIOLA, Ciro;
2016

Abstract

Aqueous solutions of indocyanine green (ICG) are spectrophotometrically and fluorimetrically studied as a function of the dye concentration. The integral absorbance concept is introduced to minimize uncertainties due to the use of only a point. This new method, provides a value of the equilibrium constant consistent with those obtained, by a different method, for safranine and thionine. The influence of ICG concentration on its fluorescence spectrum is determined. When ICG is exposed to white light degrades through the formation of free radicals. The overall kinetics of degradation is monitored spectrophotometrically and studied in an unconventional way. The results exhibit a power law, regardless of the initial concentration of dye. An apparent order of 1.5 suggests a complex mechanism where the collision between radicals is very important whilst a lifetime of 4 h it is indicative of a rapid degradation kinetics.
2016
Thermodynamic properties and photodegradation kinetics of indocyanine green in aqueous solution / DI NEZZA, Francesca; Guerra, Germano; Costagliola, Ciro; Zeppa, L.; Ambrosone, Luigi. - In: DYES AND PIGMENTS. - ISSN 0143-7208. - 134:(2016), pp. 342-347. [10.1016/j.dyepig.2016.06.012]
File in questo prodotto:
File Dimensione Formato  
Dyes and Pigments Guerra 2016.pdf

non disponibili

Dimensione 909.32 kB
Formato Adobe PDF
909.32 kB Adobe PDF   Visualizza/Apri   Richiedi una copia

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11588/871787
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 23
  • ???jsp.display-item.citation.isi??? 22
social impact