Improving hydrogen and volatile fatty acids production through pretreatment of spent coffee grounds

Consumption of coffee produces large amounts of waste in the form of spent coffee grounds (SCG), a lignocellulosic material rich in carbohydrates, proteins, and polyphenols. This abundant feedstock is promising in terms of biofuels and value-added product generation. This study investigated the impact of pretreatments, such as alkaline (NaOH), ultrasound, and static magnetic field, on SCG bioconversion in terms of biomolecule release, H2 potential and volatile fatty acids production. Following treatment, the slurry (solid and liquid fraction mixture) was utilised in anaerobic fermentation tests at varying volatile solid (VS) concentrations (23.3 and 46.7 g VS/L). The highest H2 production range, 25 – 30 mL H2/g VS, was obtained using the alkaline-pretreated SCG slurry at 23.3 g VS/L. Nevertheless, inhibition of H2 production was observed when utilising the alkaline-pretreated slurry at 46.7 g VS/L owing to the excessive use of NaOH for pretreatment and chemicals to adjust the initial pH. In contrast, increasing the VS concentration had a positive impact on volatile fatty acids accumulation, with acetic (HAc) and caproic acid being dominant. Ultrasound-pretreated SCG achieved 3260.0 mg HAceq/L at a concentration of 46.7 g VS/L.