An asymmetric synthesis of the C(21) C(26) fragment of superstolide A is described. A fragment, corresponding to a reductive ozonolysis product of superstolide, as also prepared. Comparison of spectroscopic and optical properties of the corresponding fragment obtained by degraduation of natural superstolide A allowed the confirmation of the stereochemistry of the natural product.
Studies towards the synthesis of superstolide A. Synthesis and stereochemical assignment of the C(21)-C(26) fragment of superstolide A / Zampella, Angela; D'Auria, MARIA VALERIA. - In: TETRAHEDRON-ASYMMETRY. - ISSN 0957-4166. - STAMPA. - 12:11(2001), pp. 1543-1545. [10.1016/S0957-4166(01)00281-6]
Studies towards the synthesis of superstolide A. Synthesis and stereochemical assignment of the C(21)-C(26) fragment of superstolide A
ZAMPELLA, ANGELA;D'AURIA, MARIA VALERIA
2001
Abstract
An asymmetric synthesis of the C(21) C(26) fragment of superstolide A is described. A fragment, corresponding to a reductive ozonolysis product of superstolide, as also prepared. Comparison of spectroscopic and optical properties of the corresponding fragment obtained by degraduation of natural superstolide A allowed the confirmation of the stereochemistry of the natural product.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
